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Milliken's Oil Drop Experiment

The Millikens Oil Drop Experiment was an experiment performed by Robert A. Millikan and Harvey Fletcher  in 1909 to measure the charge of an electron. This experiment proved to be very crucial in the physics community.

Millikens Oil Drop Experiment Definition

In the experiment, Milliken allowed charged tiny oil droplets to pass through a hole into an electric field. By varying the strength of the electric field the charge over an oil droplet was calculated, which always came as an integral value of ‘e.’

Millikan Oil Drop Experiment

Apparatus of the Milliken’s Oil Drop Experiment

The apparatus for the experiment was constructed by Milliken and Fletcher. It incorporated two metal plates held at a distance by an insulated rod. There were four holes in the plate, out of which three were there to allow light to pass through them and one was there to allow viewing through the microscope.

Ordinary oil wasn’t used for the experiment as it would evaporate by the heat of the light and so could cause an error in the Millikens Oil Drop Experiment. So, the oil that is generally used in a vacuum apparatus which is of low vapour pressure was used.

Milliken’s Oil Drop Experiment Procedure

  • Oil is passed through the atomizer from where it came in the form of tiny droplets. They pass the droplets through the holes present in the upper plate of the apparatus.
  • The downward motions of droplets are observed through a microscope and the mass of oil droplets, then measure their terminal velocity.
  • The air inside the chamber is ionized by passing a beam of X-rays through it. The electrical charge on these oil droplets is acquired by collisions with gaseous ions produced by ionization of air.
  • The electric field is set up between the two plates and so the motion of charged oil droplets can be affected by the electric field.
  • Gravity attracts the oil in a downward direction and the electric field pushes the charge upward. The strength of the electric field is regulated so that the oil droplet reaches an equilibrium position with gravity.
  • The charge over the droplet is calculated at equilibrium, which is dependent on the strength of the electric field and mass of droplet.

Milliken’s Oil Drop Experiment Calculation

F up = F down

F up = Q . E

F down = m.g

Q  is  an  electron’s  charge,  E  is  the  electric  field,  m  is  the  droplet’s  mass,  and  g  is  gravity.

One can see how an electron charge is measured by Millikan. Millikan found that all drops had charges that were 1.6x 10 -19 C multiples.

Milliken’s Oil Drop Experiment Conclusion

The charge over any oil droplet is always an integral value of e (1.6 x 10 -19 ). Hence, the conclusion of  Millikens Oil Drop Experiment is that the charge is said to be quantized, i.e. the charge on any particle will always be an integral multiple of e.

Frequently Asked Questions – FAQs

What did millikan’s oil drop experiment measure.

Millikan oil-drop test, the first simple and persuasive electrical charge calculation of a single electron. It was first conducted by the American physicist Robert A. in 1909. He discovered that all the drops had charges that were simple multiples of a single integer, the electron’s fundamental charge.

What is the importance of Millikan’s oil drop experiment?

The experiment with Millikan is important since it defined the charge on an electron. Millikan used a very basic, very simple system in which the behaviour of gravitational, electrical, and (air) drag forces were controlled.

What did Millikan conclude after performing his oil drop experiment?

An integral multiple of the charge on an electron is the charge on every oil decrease. About an electric force. In a relatively small amount, the charge and mass of the atom must be condensed.

Why charges are quantized?

Charges are quantized since every object’s charge (ion, atom, etc.) Charge quantization, therefore, implies that no random values can be taken from the charge, but only values that are integral multiples of the fundamental charge (proton / electron charge).

Can charge be created or destroyed?

The Charge Conservation Law does not suggest that it is difficult to generate or remove electrical charges. It also means that any time a negative electrical charge is produced, it is important to produce an equal amount of positive electrical charge at the same time so that a system’s overall charge does not shift.

For more information about quantum physics , download BYJU’S-The learning app to play store and app store.

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The oil drop experiment

how to do the oil drop experiment

We have considered the forces that exist in a solid between two adjacent molecules and we have therefore assumed the existence of these molecules. The follow- ing simple experiment can be used to give a rough idea of the size of a molecule, and hence an atom. The radius r of a small drop of oil is found and the volume of the drop calculated. The drop is now placed on the surface of some dust-covered water and the drop spreads out into a roughly circular patch of height h and radius R. The diameter of the patch is measured and hence the radius R is found. Now the volume of the original drop (4/3πr 3 ) is the same as that of the film (πr 2 h); therefore, if h is the thickness of the film and the original volume of the drop is known the thickness of the film can be found. Now the thickness of the oil film cannot be less than the size of a molecule and so the size of a molecule of oil must be equal to or less than the thickness of the film. If the thickness of the film (h) can be found this is the upper limit of the size of an oil molecule.

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Who Did the Oil Drop Experiment?

The Oil Drop Experiment was performed by the American physicist Robert A Millikan in 1909 to measure the electric charge carried by an electron . Their original experiment, or any modifications thereof to reach the same goal, are termed as oil drop experiments, in general.

Oil Drop Experiment

What is the Oil Drop Experiment?

In the original version, Millikan and one of his graduate students, Harvey Fletcher, took a pair of parallel horizontal metallic plates. A uniform electric field was created in the intermediate space by applying a potential difference between them. The plates were held apart by a ring of insulating material. The ring had four holes, three for allowing light to illuminate the setup, and the fourth one enabled a microscope for viewing. A closed chamber with transparent walls was fitted above the plates.

At the beginning of the experiment, a fine mist of oil droplets was sprayed into the chamber. In modern setups, an atomizer replaces the oil droplets. The oil was so chosen such that it had a low vapor pressure and capable of charging. Some of the oil drops became electrically charged by friction as they forced their way out of the nozzle. Alternatively, charging could also be induced by incorporating a source of ionizing radiation , such as an X-Ray tube, in the apparatus. The droplets entered the space between the plates and raised or fell, according to the requirement, by varying plate voltage.

Millikan Oil Drop Experiment

In terms of the present-day arrangement, when the electric field is turned off, the oil drops fall between the plates under the action of gravity only. The friction with the oil molecules in the chamber makes them reach their terminal velocity fast. The terminal velocity is the constant speed that a freely falling object eventually reaches when the resistance of the medium through which it is falling prevents further acceleration . Once the field is turned on, the charged drops start to rise. This motion happens since the electric force directed upwards is stronger than the gravitational force acting downwards. One charged drop is selected and kept at the center of the field of view of the microscope after allowing all other drops to fall by alternately switching off the voltage source. The experiment is conducted with this drop.

Theory and Calculations

First, the oil drop is allowed to fall in the absence of an electric field, and its terminal velocity, say v 1 , is found out. Using Stokes’ law, the drag force acting on the drop is calculated using the following formula.

Here r is the radius of the drop and ɳ, the viscosity of air.

The weight of the drop, w’, which is the product of its mass and acceleration due to gravity g, is given by the equation,

where ρ is the density of the oil.

However, what we need here is the apparent weight w of the drop in the air given by the difference of the actual weight and the upthrust of the air. We can express w  by the following formula.

Here ρ air denotes the density of air.

When the drop attains terminal velocity, then it has no acceleration. Hence, the total force acting on it must be zero. That means,

The above equation can be used to find out the value of r. Once r is calculated, the value of w can easily be found out from equation (i) marked above.

Oil Drop Experiment Free Body Diagram

Now after turning on the electric field between the plates, the electric force F E acting on the drop is,

Where E is the electric field and q the charge on the oil drop. For parallel plates, the formula for E is,

Here V is the potential difference and d the distance between the plates. That implies,

Now if we adjust V to make the oil drop remain steady at a point, then

Thus, the value of q can be calculated.  By repeatedly applying this method to multiple oil droplets, the electric charge values on individual drops were always found to be integer multiples of the smallest value. This lowest charge could be nothing but the charge on the elementary particle, electron. By this method, the electronic charge was calculated to be approximate, 1.5924×10 −19  C, making an error of 1% of the currently accepted value, 1.602176487×10 −19 C. All subsequent research pointed to the same value of charge on the fundamental particle.

Millikan was able to measure both the amount of electric force and magnitude of electric field on the tiny charge of an isolated oil droplet and from the data determine the magnitude of the charge itself. Millikan’s oil drop experiment proved that the electric charge is quantized in nature. The electric charge appears in quanta of magnitude 1.6 X 10 -19 C in oil droplets.

Robert Millikan’s Oil Drop Experiment Animation

Millikan’s oil drop experiment and the atomic theory.

Until the time of the Oil Drop Experiment, the world had little or no knowledge of what is present inside an atom . Earlier experiments by the English Physicist J.J. Thomson had shown that atoms contain some negatively charged particles of masses significantly smaller than that of the hydrogen atom. Nevertheless, the exact value of the charge carried by these subatomic particles remained in the dark. The very existence of these particles was not accepted by many due to a lack of concrete evidence. Thus, the atomic model was shrouded in mystery. In this scenario, with Millikan’s groundbreaking effort to quantify the charge on an electron, the atomic theory came of age in the early years of the twentieth century.

Controversy about the Oil Drop Experiment and Discovery

Robert Millikan was the sole recipient of the Nobel Prize in Physics in 1923 for both his work in this classic experiment and his research in the photoelectric effect . Fletcher’s work on the oil drop project, however, was not recognized. Many years later, the writings of Fletcher revealed that Millikan wished to take the sole credit for the discovery in exchange for granting him a Ph.D. and helping him secure a job after his graduation.

The beauty of the oil drop experiment lies in its simple and elegant demonstration of the quantization of charge along with measuring the elementary charge on an electron that finds widespread applications to this day. With the progress of time, considerable modifications have been made to the original setup resulting in obvious perfection in the results. Still, no substantial deviation from the results of the classical experiment could yet be found.

  • Robert Millikan and Harvey Fletcher conducted the oil drop experiment to determine the charge of an electron. The experiment was the first direct and riveting measurement of the electric charge of a single electron.
  • They suspended tiny charged droplets of oil between two metal electrodes by balancing downward gravitational force with upward drag and electric forces.
  • They later used their findings to determine the mass of the electron.
  • Kentchemistry.com
  • Physics.utah.edu
  • Nobelprize.org
  • Ffden-2.phys.uaf.edu
  • Chem.libretexts.org

Article was last reviewed on Thursday, February 2, 2023

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COMMENTS

  1. Millikens Oil Drop Experiment

    Millikens Oil Drop Experiment Definition. In the experiment, Milliken allowed charged tiny oil droplets to pass through a hole into an electric field. By varying the strength of the electric field the charge over an oil droplet was calculated, …

  2. Oil drop experiment

    The oil drop experiment was performed by Robert A. Millikan and Harvey Fletcher in 1909 to measure the elementary electric charge (the charge of the electron). The experiment took place in the Ryerson Physical Laboratory at the University of Chicago. Millikan received the Nobel Prize in Physics in 1923. The experiment observed tiny electrically charged droplets of oil located betwee…

  3. Millikan oil-drop experiment

    At the start of the experiment, an atomizer sprays a fine mist of oil droplets into the upper portion of the chamber. Under the influence of gravity and air resistance, some of the oil droplets fall through a small hole cut in the top …

  4. The oil drop experiment

    The oil drop experiment. We have considered the forces that exist in a solid between two adjacent molecules and we have therefore assumed the existence of these molecules. The follow- ing simple experiment can be used to give a …

  5. Millikan's Oil Drop Experiment

    Robert Millikan and Harvey Fletcher conducted the oil drop experiment to determine the charge of an electron. The experiment was the first direct and riveting measurement of the electric charge of a single electron.

  6. The Millikan Oil-Drop Experiment

    This experiment first described by [Millikan, 1913] is based on the fact that different forces act on an electrically charged oil drop moving in the homogeneous electric field of a plate capacitor …